Mathematical Quantum Mechanics
Vector Space
Vector Space $V$ over $\Complex$
$^\forall u,v,w\in V$ and $\alpha, \beta \in \Complex$
- $u+v=v+u$
- $(u+v)+w=u+(v+w)$
- $^\exist \mathbf{0}$ such that $\mathbf{0}+v=v$
- $^\exist -v$ such that $v+(-v)=0$
- $\alpha(\beta v)=(\alpha\beta)v$
- $(\alpha+\beta)v=\alpha v + \beta v$
- $\alpha(v+w) = \alpha v + \alpha w$
- $^\exist \mathbf{1}$ such that $\mathbf{1}\cdot(v)=v$
Example
$3$-dimensional vector:
\[\vec{v}=(x,y,z)^T=x\hat{e_1}+y\hat{e_2}+z\hat{e_3}\] \[\left.\begin{matrix}\hat{e_1}=(1,0,0)^T\\\hat{e_2}=(0,1,0)^T\\\hat{e_3}=(0,0,1)^T\end{matrix}\right\}=\text{standard basis}\]$n$-dimensional vector:
\[\begin{aligned}\hat{e_k}&=(0,0,\cdots,0,1,0,\cdots,0)^T\\\vec{v}&=\sum_{k=1}^n v_k\hat{e_k}\end{aligned}\]Inner Product $V^*\times V\rightarrow\Complex$
Conjugate Transpose; Hermitian Transpose
$V^\ast=\overline{V^T}=\overline{V}^T$
$V_{ij}^\ast=\overline{V_{ji}}$
- $\langle\vec{v},\vec{v}\rangle\geq0$ with equality iff $\vec{v}=0$
- $\langle\vec{v},\vec{w}\rangle=\langle\vec{w},\vec{v}\rangle^\ast$
- $\langle\alpha\vec{v},\vec{w}\rangle=\alpha^\ast\langle\vec{v},\vec{w}\rangle\\langle\vec{v},\alpha\vec{w}\rangle=\alpha\langle\vec{v},\vec{w}\rangle$
Example
\[\begin{aligned}\vec{v}&=\sum_k v_k\hat{e_k}\\\vec{w}&=\sum_k w_k\hat{e_k}\\\langle\vec{v},\vec{w}\rangle&=\sum_{k,l}v_k^{\ast}w_l\underbrace{\hat{e_k}^\dagger\cdot\hat{e_l}}_{\delta_{k,l}}=\sum_kv_k^{\ast}w_k\end{aligned}\] \[\begin{aligned}\vec{v}&=\sum_kv_k\hat{e_k}\\\vec{v}^\dagger&=\sum_kv_k^\ast\hat{e_k}^T=(\vec{v}^\ast)^T\\\langle\vec{v},\vec{w}\rangle&=\vec{v}^\dagger\cdot\vec{w}\\\langle\vec{w},\vec{v}\rangle&=\sum_kw_k^\ast v_k=\left(\sum_kv_k^\ast w_k\right)^\ast=\langle\vec{v},\vec{w}\rangle^\ast\end{aligned}\]Vector Space and Dirac Notation
| Vector Space | Dirac Notation |
|---|---|
| $\vec{v}$ | $\vert v\rangle$ |
| $\vec{v}^\dagger$ | $\langle v \vert$ |
| $\langle v,w\rangle=\langle w,v\rangle^\ast$ | $\langle v\vert w\rangle=\langle w\vert v\rangle^\ast$ |
Example
\[\begin{aligned}\vert 0\rangle&=\begin{pmatrix}1\\0\end{pmatrix}, && \vert 1\rangle=\begin{pmatrix}0\\1\end{pmatrix}\\\vert v\rangle&=\alpha\vert 0\rangle+\beta\vert 1\rangle\\\langle v\vert v\rangle&=\vert\alpha\vert^2+\vert\beta\vert^2=1 && \text{(normalization)}\\\implies \alpha&=e^{i\phi_1}\cos{\frac{\theta}{2}}\\\beta&=e^{i\phi_2}\sin{\frac{\theta}{2}}\end{aligned}\]Function Space
\[\begin{aligned}f(x) : [a,b] &&\rightarrow&&\Complex&: \text{complex-valued function}\\g(x) : [a,b] &&\rightarrow&&\Complex&: \text{complex-valued function}\\\sigma(x) : [a,b] &&\rightarrow&&\R&: \text{weight function}\end{aligned}\]Inner Product of Two Functions, $\langle f,g\rangle$
\[\langle f,g\rangle=\int_a^b f^\ast(x)g(x)\sigma(x)dx\] \[\left\{\phi_n(x)\right\}_{n=1}^{\infin}: \text{basis function}\] \[f(x)=\sum_{n=1}^{\infin}C_n\phi_n(x)\] \[\begin{aligned}\langle\phi_j,f\rangle&=\int\phi_j(x)\sum_nC_n\phi_n(x)dx\\&=\sum_nC_n\langle\phi_j,\phi_n\rangle\end{aligned}\]Suppose that $\langle\phi_j,\phi_n\rangle=N_j\delta_{n,j}$ and $N_j=\langle\phi_j,\phi_j\rangle$,
\[\implies C_j=\frac{1}{N_j}\langle\phi_j,f\rangle=\frac{\langle\phi_j,f\rangle}{\langle\phi_j,\phi_j\rangle}\]Generalized Basis Expansion
$f(x)$ is represented by an expansion over basis of orthonormal functions $\left{\phi_n(x)\right}_{n=1}^\infin$
\[f(x)=\sum_nC_n\phi_n(x)\]The coefficients can be determined as
\[C_n=\frac{\langle\phi_n,f\rangle}{\langle\phi_n,\phi_n\rangle}\]Example (Fourier Series)
\[\begin{aligned}f(x)&=\sum_{n=1}^\infin b_n\sin{nx},&&x\in[-\pi,\pi]\\\phi_n(x)&=\sin{nx},&&n=1,2,\cdots,&&x\in[-\pi,\pi]\\\sigma(x)&=1\\\langle\phi_n,\phi_m\rangle&=\int_{-\pi}^\pi\sin{nx}\sin{mx}dx=\pi\delta_{n,m}\\b_n&=\frac{\langle\phi_n,f\rangle}{\langle\phi_n,\phi_n\rangle}=\frac{1}{\pi}\int_{-\pi}^\pi f(x)\sin{nx}dx\end{aligned}\]Orthogonal Polynomials
$\begin{aligned}f(x)=\sum_nC_nX^n,&&x\in[-1,1], &&\sigma(x)=1\end{aligned}$